Home Chemistry Chemical Analysis Mix H 2 S in the presence of HCl precipitates ΙΙ…
Chemistry Chemical Analysis Mix Single Correct MCQ
Published on: August 14, 2026

H 2 S in the presence of HCl precipitates ΙΙ group but not Ι V group because

A
HCl activates H 2 S
B
HCl increases concentration of Cl –
C
HCl decreases concentration of S 2–
D
HCl lowers the solubility of H 2 S in solution

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Text Solution

Verified by Experts
The correct answer is:
C

H 2 S 2H + + S 2– ; HCl H 2+ + Cl – .

Due to common ion effect, the ionisation of H 2 S is suppressed and thus low concentration of S 2– ions is obtained. This much of S 2– ions concentration is enough to precipitate only II nd group cations (because of the low K SP of II nd group sulphides).

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